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Polymer-supported solution synthesis of a heptaglucoside having phytoalexin elicitor activity

✍ Scribed by R. Verduyn; P. A. M. van der Klein; M. Douwes; G. A. van der Marel; J. H. van Boom

Book ID: 104589550
Publisher: Elsevier Science
Year: 2010
Tongue: English
Weight: 232 KB
Volume: 112
Category: Article
ISSN: 0165-0513
DOI: 10.1002/recl.19931120707

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✦ Synopsis

Abstract

An efficient synthesis of methyl heptaglucoside 2 using poly(ethyleneglycol)monomethyl ether as a polymer support is described. Elongation of the acceptor 11, anchored via a succinoyl linkage to PEG, with the appropriate glycosyl donors 4–6 and intermittent protective group manipulations gave fully protected heptamer 18. Deprotection of 18 furnished, after purification as its peracetate, title compound 2 in a good overall yield.

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