Polymer supported naphthalene-catalysed sodium reactions
β Scribed by van den Ancker, Tania R.; Love, Cameron J.
- Book ID
- 119942265
- Publisher
- Royal Society of Chemistry
- Year
- 2007
- Tongue
- English
- Weight
- 107 KB
- Volume
- 5
- Category
- Article
- ISSN
- 1477-0520
- DOI
- 10.1039/B710308E
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π SIMILAR VOLUMES
The reaction of functional&d mono or dichlorinated materials la-6a with an excess of lithium and a catalytic amount of a napbthalene supported polymer (P-152, easily prepared by radical copolymerisation of 2\_vinylnaphthalene, styrene and divinylbenzene) in THF either in the presence (Barbier-type c
The reaction of functionalised mono or dichlorinated materials la-6a with an excess of lithium and a catalytic amount of a naphthalene (PN) or biphenyl (PB) supported polymer (eassily prepared by radical copolymerisation of 2-vinylnaphthalene or 4-vinylbiphenyl with vinylbenzene and divinylbenzene)
Polymer Supported Naphthalene-Catalyzed Lithiation Reactions. -Lithiation of functionalized organic chlorides (I) is effectively promoted by a naphthalene supported polymer. Quenching with electrophiles (II) leads to the expected products (III). Dichlorides (IV) and (VII) undergo an analogous react