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Polymer-Supported Chiral Co(Salen) Complexes: Synthetic Applications and Mechanistic Investigations in the Hydrolytic Kinetic Resolution of Terminal Epoxides

✍ Scribed by Annis, D. Allen; Jacobsen, Eric N.


Book ID
115527402
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
130 KB
Volume
121
Category
Article
ISSN
0002-7863

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Polyglycerol-Supported Co- and Mn-salen
✍ Maryam Beigi; Sebastian Roller; Rainer Haag; Andreas Liese πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 291 KB πŸ‘ 1 views

## Abstract In this report we demonstrate the suitability of hyperbranched polyglycerol as high‐loading support for asymmetric catalysis. A polyglycerol‐supported unsymmetrical salen ligand was prepared and purified by means of ultrafiltration. The polymeric ligand was metalated with cobalt acetate