fhe free radical polymerization of styrene in benzene was studied theoretically and experimentally over ranges of monomer and catalyst (AIEN) concentrations and temperature in an isothermal, stirred batch reactor. Molecular weight distributions were measured with a gel permeation chromatograph. Tung
Polymer reactors and molecular weight distribution: Part I. Free radical polymerization in a continuous stirred-tank reactor
β Scribed by J. H. Duerksen; A. E. Hamielec; J. W. Hodgins
- Publisher
- American Institute of Chemical Engineers
- Year
- 1967
- Tongue
- English
- Weight
- 562 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0001-1541
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## Abstract **Summary:** Using the authors' previously developed method for the general kinetic analysis of nonβlinear irreversible polymerizations, the simulation of free radical homogeneous polymerization systems with terminal branching and chain transfer to polymer has been carried out for conti
Mole balance for the molecular weight distribution in homogeneous continuos-flow stirred tank reactors (HCSTRs) for reversible step-growth polymerization has been written. The relation for the moment generating function G is found to be a nonlinear ordinary differential equation and has been solved