Molecular-Weight-Distribution Modelling of Radical Polymerization in Batch and Continuous Reactors with Transfer to Polymer Leading to Gel Formation

Molecular Weight Distribution in Living

Molecular Weight Distribution in Living Polymerization Proceeding with Reshuffling of Polymer Segments due to Chain Transfer to Polymer with Chain Scission, 2. Monte Carlo Simulation of Polymer Reshuffling Proceeding with Disproportionation of Chain Functionalities

✍ Ryszard Szymanski; Jolanta Baran 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 630 KB

Dependencies of PDI on monomer conversion (a = ([M] 0 -[M])/[M] 0 ) for systems with [M] 0 /[I] 0 = 10 2 , computed for various (shown in the Figure) values of (k tr / k p ) N ([M] 0 /[I] 0 ). Dotted lines: systems without disproportionation (Ref. [1] ), circles: systems with disproportionation.