Polymer- bound flavins. III. Effects of coil dimension and substrate structure on reaction kinetics in water/2-propanol mixtures

Effects of solvent on the reactions of c

Effects of solvent on the reactions of coordination complexes. part 24. kinetics of base hydrolysis of some (aminomonocarboxylato)(tetraethylene-pentamine)cobalt(III) complexes in methanol+water media: The role of substrate hydrophobicity and solvent structure

✍ Anadi C. Dash; Achyuta N. Acharya; Smrutiprava Das 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 199 KB 👁 2 views

The kinetics of base hydrolysis of some (aminomonocarboxylato)(tetraethylenepentamine)cobalt(III) complexes, [(tetren have been investigated in methanol-water media (0-80 vol % MeOH) at 15.0 Յ tЊC Յ 40.0 (0.02 mol dm Ϫ3 NaOH). The second-order rate constant at zero ionic strength, k 2 Њ, increases