Polyhedral boron derivatives of porphyrins and phthalocyanines
✍ Scribed by Vladimir I. Bregadze; Igor B. Sivaev; Detlef Gabel; Dieter Wöhrle
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 628 KB
- Volume
- 05
- Category
- Article
- ISSN
- 1088-4246
- DOI
- 10.1002/jpp.544
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## Abstract A theoretical comparative study of complexes of porphyrin (P), porphyrazine (Pz), and phthalocyanine (Pc) with metal (M) = Fe, Co, Ni, Cu, and Zn has been carried out using a DFT method. The calculations provide a clear elucidation of the ground states for the MP/Pz/Pc molecules and for
## Abstract The syntheses of tetraphenylporphyrins 1b, d, e containing four methacryloyloxy or 2,4‐hexadienoyloxy substituents and phthalocyanines 2b, d containing four methacryloyloxy substituents are described. Copolymerizations with styrene in solution were investigated in detail, and the compos
## Abstract The synthesis and photophysical properties are described for a series of porphyrin, phthalocyanine and pyrazinoporphyrazine derivatives which bear four or eight peripheral fluorenyl substituents as antennae. Representative examples are 5,10,15,20‐tetra(9,9‐dihexyl‐9__H__‐fluoren‐2‐yl)po