Polymer-bound porphyrins and their precursors, 11. Syntheses and polymerization of methacryloyloxy and 2,4-hexadienoyloxy derivatives of porphyrins and phthalocyanines

✍ Scribed by Holger Eichhorn; Michael Sturm; Dieter Wöhrle

• Publisher: John Wiley and Sons
• Year: 1995
• Tongue: English
• Weight: 827 KB
• Volume: 196
• Category: Article
• ISSN: 1022-1352
• DOI: 10.1002/macp.1995.021960107

✦ Synopsis

Abstract

The syntheses of tetraphenylporphyrins 1b, d, e containing four methacryloyloxy or 2,4‐hexadienoyloxy substituents and phthalocyanines 2b, d containing four methacryloyloxy substituents are described. Copolymerizations with styrene in solution were investigated in detail, and the compositions and molecular weights of the copolymers were determined. In addition, homopolymerizations in solution were carried out. After coating on quartz or KBr plates, the thermal and photochemically induced homopolymerizations were investigated fundamentally.