Poly(ethylene oxide) macromonomers. 8. Preparation and polymerization of ι-hydroxypoly(ethylene oxide) macromonomers
✍ Scribed by Ito, Koichi; Hashimura, Kazuo; Itsuno, Shinichi; Yamada, Eiichi
- Book ID
- 120032028
- Publisher
- American Chemical Society
- Year
- 1991
- Tongue
- English
- Weight
- 585 KB
- Volume
- 24
- Category
- Article
- ISSN
- 0024-9297
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## Abstract A novel __α__,__ω__‐heterofunctional poly(ethylene oxide) (PEO) macromonomer possessing methacryloyl and thienyl end groups was prepared by ring‐opening polymerization of ethylene oxide initiated by potassium thienylethoxide and termination of the living PEO ends with methacryloyl chlor
## Abstract **Summary:** __α__,__ω__‐Hybrid (hetero‐telechelic) poly(ethylene oxide) (PEO) macromonomers carrying both cationic and radical or anionic polymerizable vinyl end groups were newly synthesized by the living anionic polymerization of ethylene oxide (EO) initiated with partially K‐alkoxid