Single-crystal X-ray study T = 296 K Mean '(C±C) = 0.004 A Ê Disorder in main residue R factor = 0.025 wR factor = 0.065 Data-to-parameter ratio = 16.7 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.
Poly[disilver(I)(Ag—Ag)-μ-4-chlorobenzoato-μ-piperazine]
✍ Scribed by Yang, Song ;Zou, Ying ;Zhu, Hai-liang
- Publisher
- International Union of Crystallography
- Year
- 2005
- Tongue
- English
- Weight
- 199 KB
- Volume
- 61
- Category
- Article
- ISSN
- 1600-5368
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📜 SIMILAR VOLUMES
In the title compound, [Ag~2~(C~9~H~12~N~4~)~2~]Cl~2~·0.5H~2~O, each Ag^I^ atom is coordinated by two C atoms of two heterocyclic carbene ligands, displaying a nearly linear geometry. The Ag—Ag separation is quite long, indicating a very weak metal–metal interaction.
In the layer structure of the title polymeric complex, {[Ag 2 (C 7 H 5 O 6 S) 2 (H 2 O) 3 ]ÁH 2 O} n , both substituted benzenesulfonate anions use two of their sulfonyl O atoms to link to three Ag atoms and their double-bond carbonyl O atom to another Ag atom in a " 4 -bonding mode. The two symmetr
Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.013 A Ê Disorder in main residue R factor = 0.055 wR factor = 0.148 Data-to-parameter ratio = 16.0 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.