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Poly[diaqua­di-μ3-malonato-μ-pyrazine-dinickel(II)]

✍ Scribed by Liu, Ying ;Dou, Jianmin ;Wang, Daqi ;Ma, Guolin ;Li, Dacheng

Publisher
International Union of Crystallography
Year
2005
Tongue
English
Weight
260 KB
Volume
61
Category
Article
ISSN
1600-5368

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The Ca atom in the title compound, {[Ca(HO 2 CC 6 H 4 OCH 2 -CO 2 ) 2 (H 2 O) 2 ]Á2H 2 O} n , is eight-coordinate. The HO 2 CC 6 H 4 -OCH 2 CO 2 À monoanion binds in a chelating mode; it also functions as a bridge, linking adjacent Ca atoms into a zigzag chain. Hydrogen bonds link the chains into a