Polychronic Kinetics of Chemical Reactions with the Blending of Rate Constants
β Scribed by Goldanskii, V. I.; Kozhushner, M. A.; Trakhtenberg, L. I.
- Book ID
- 127373972
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 114 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0022-3654
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π SIMILAR VOLUMES
This article is concerned with the application of a new method to recover the rate constants in chemical reactions. The method is based on treating the unknown parameters as time dependent. With appropriate experimental data the unknown rate constants are guided from an arbitrary initial condition t
## Abstract Tungsten hexacarbonyl was studied by chemical ionization mass spectrometry using carbon monoxide as reagent gas. The variation of the relative abundances of ions as a function of reactant gas pressure was used for evaluating the relative rate constants for consecutive reactions. The res