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Ion–molecule reactions by chemical ionization: Determination of rate constants

✍ Scribed by Sandro Torroni; Giuseppe Innorta; Francesco Scagnolari; Antonio Foffani; Ornella Curcuruto

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
276 KB
Volume
28
Category
Article
ISSN
1076-5174

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✦ Synopsis

Abstract

Tungsten hexacarbonyl was studied by chemical ionization mass spectrometry using carbon monoxide as reagent gas. The variation of the relative abundances of ions as a function of reactant gas pressure was used for evaluating the relative rate constants for consecutive reactions. The results are in agreement with the rate constant ratios obtained from ion trap mass spectrometric data.

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