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Poly[bis(μ2-pyridine-2,6-dicarboxylato)cobalt(II)disodium(I)]

✍ Scribed by Liu, Fu-Chen ;Ouyang, Jie

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
886 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

The title compound, [Na 2 Co(C 7 H 3 NO 4 ) 2 ] n , is isostructural with the nickel(II) analog. In the crystal structure, the Co cation is coordinated by two N atoms and four O atoms of two pyridine-2,6-dicarboxylate groups with a strongly distorted octahedral geometry. The Na cations are coordinated by six O atoms of pyridine-2,6-dicarboxylate anions in an irregular geometry. The bis(pyridine-2,6-dicarboxylato)cobalt complexes are connected by the sodium cations into a threedimensional coordination network.

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