Poly[bis(guanidinium) [diaquabis(μ3-hydrogencitrato)-μ2-oxalato-dineodymium(III)] heptahydrate]
✍ Scribed by Grigoriev, Mikhail S. ;Den Auwer, Christophe ;Meyer, Daniel ;Moisy, Philippe
- Publisher
- International Union of Crystallography
- Year
- 2006
- Tongue
- English
- Weight
- 600 KB
- Volume
- 62
- Category
- Article
- ISSN
- 1600-5368
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✦ Synopsis
The structure of the title compound,
contains anionic layers in which every Nd atom is linked to three other Nd atoms by citrate anions and to one Nd atom by the centrosymmetric oxalate anion. The Nd atoms are ten-coordinated; their coordination polyhedra form pairs sharing one edge owing to bridging by O atoms of carboxylate groups of citrate anions.
📜 SIMILAR VOLUMES
The title yttrium(III) coordination polymer, {[Y~2~(C~7~H~3~NO~4~)~2~(C~2~O~4~)(H~2~O)~4~]·3H~2~O}~__n__~, has a pyridine-3,4-dicarboxylate (PDC) and oxalate (ox) bridged layer-type structure. The central yttrium ion exhibits a distorted dodecahedral configuration, coordinated by eight O atoms from
bis[aqua-(l-sulfato-j 3 O,O 0 0 0 :O 0 0 00 0 0 )(l-sulfato-j 4 O,O 0 0 0 :O 0 0 00 0 0 ,O 0 0 00 0 00 0 0 )-(sulfato-jO)terbate(III)] tetrahydrate]