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Polybenzoxazinones and poly(benzoxazinone-phenylquinoxaline)s containing pendant imide groups

✍ Scribed by C. Hamciuc; E. Hamciuc; M. Bruma; N.M. Belomoina


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
419 KB
Volume
32
Category
Article
ISSN
0014-3057

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✦ Synopsis


l?olybcnzoxazinones and poly(benzoxazinone-phenylquinoxaline)s containing pendant imide groups have been synthesized by cyclopolycondensation of diacid chlorides which contain preformed imide rings, with 3,3'-dicarboxy-4,4'-diaminodiphenyl-methane or with mixtures of the latter with a bis(amino-phenylquinoxaline).

The low temperature solution polycondensation technique afforded poly(amic-acid)s in the first step, which underwent thermal or chemical cyclodehydration, in the second step. The ,c:[clodehydration process of the poly(amic-acid)s has been studied by infrared, thermogravimetric and dlfierential scanning calorimetry analyses. The solubility, thermal stability and glass transition temperature of these polymers have been studied and compared with related heterocyclic polymers that have been previously reported.


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