Polybenzoxazinones and poly(benzoxazinone-phenylquinoxaline)s containing pendant imide groups
✍ Scribed by C. Hamciuc; E. Hamciuc; M. Bruma; N.M. Belomoina
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 419 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0014-3057
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✦ Synopsis
l?olybcnzoxazinones and poly(benzoxazinone-phenylquinoxaline)s containing pendant imide groups have been synthesized by cyclopolycondensation of diacid chlorides which contain preformed imide rings, with 3,3'-dicarboxy-4,4'-diaminodiphenyl-methane or with mixtures of the latter with a bis(amino-phenylquinoxaline).
The low temperature solution polycondensation technique afforded poly(amic-acid)s in the first step, which underwent thermal or chemical cyclodehydration, in the second step. The ,c:[clodehydration process of the poly(amic-acid)s has been studied by infrared, thermogravimetric and dlfierential scanning calorimetry analyses. The solubility, thermal stability and glass transition temperature of these polymers have been studied and compared with related heterocyclic polymers that have been previously reported.
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