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Poly(arylene ether)s from new biphenols containing imidoarylene and dicyanoarylene moieties

✍ Scribed by Antisar R. Hlil; Yuezhong Meng; Allan S. Hay; Imad A. Abu-Yousef

Publisher: John Wiley and Sons
Year: 2000
Tongue: English
Weight: 120 KB
Volume: 38
Category: Article
ISSN: 0887-624X
DOI: 10.1002/(sici)1099-0518(20000415)38:8<1318::aid-pola16>3.0.co;2-d

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✦ Synopsis

Novel poly(arylene ether)s were synthesized from new biphenol monomers 14 -16 1 containing imido-or dicyanoarylene groups. The syntheses of these polymers were carried out in tetramethylene sulfone in the presence of anhydrous K 2 CO 3, by a nucleophilic substitution condensation between the biphenol and activated difluoro compounds to give high molecular weight polymers. All the polymers have high T g 's and good thermal stability as determined from DSC and TGA analysis. Inherent viscosities of these polymers are in the range of 0.33-0.63 dL/g. They are amorphous and readily soluble in NMP, DMF, and DMSO. The glass-transition temperatures of the polymers range from 248 -295 °C.

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