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Poly[(3,5-di-tert-butyl-4-hydroxyphenyl)acetylene] and its polyradical derivative

✍ Scribed by Nishide, Hiroyuki; Yoshioka, Naoki; Inagaki, Katsunari; Kaku, Takahiko; Tsuchida, Eishun


Book ID
126167341
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
846 KB
Volume
25
Category
Article
ISSN
0024-9297

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Synthese von 3,5-Di-tert-butyltyrosin un
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## Abstract Die Aminosäuren 3,5‐Di‐__tert__‐butyltyrosin (**1a**) und (3,5‐Di‐__tert__‐butyl‐4‐hydroxyphenyl)glycin (**2a**) werden synthetisiert. Beide Aminosäuren dürften für die Spin‐Markierung von Peptiden geeignet sein.

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A photochemical precursor to a pendant conjugated polyradical has been synthesized, poly [3,5-di-tert-butyl-4-[(2,4,6-tri-tert-butylphenyl)oxalato]phenylacetylene], 3. Irradiation of 3 at 77 K in the solid state at õ 300 nm yielded poly(3-5-ditert-butyl-2-oxyphenyl acetylene), 2, with 30-40% of the