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Poly [(3,5-di-tert-butyl-4-hydroxyphenyl)acetylene]: formation of a conjugated stable polyradical

✍ Scribed by Nishide, Hiroyuki; Yoshioka, Naoki; Inagaki, Katsunari; Tsuchida, Eishun


Book ID
120303748
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
306 KB
Volume
21
Category
Article
ISSN
0024-9297

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A photochemical precursor to a pendant conjugated polyradical has been synthesized, poly [3,5-di-tert-butyl-4-[(2,4,6-tri-tert-butylphenyl)oxalato]phenylacetylene], 3. Irradiation of 3 at 77 K in the solid state at Γ΅ 300 nm yielded poly(3-5-ditert-butyl-2-oxyphenyl acetylene), 2, with 30-40% of the