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Poly[2,4-bis(chloroamino)-6-vinyl-1,3,5-triazine] as a recyclable oxidizing agent of alcohols

✍ Scribed by Shuji Kondo; Shinya Kawasoe; Mari Ohira; Tadashi Atarashi; Kazahisa Ikeda; Hideo Kunisada; Yasuo Yuki

Publisher: John Wiley and Sons
Year: 1995
Tongue: English
Weight: 235 KB
Volume: 16
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.1995.030160410

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✦ Synopsis

A polymer containing dichlorotriazine moiety was prepared readily by the reaction of poly(2,4-diamino-6-vinyl-l,3,5-triazine) with tert-butyl hypochlorite. This polymer oxidizes various primary and secondary alcohols to the corresponding carbonyl compounds under mild conditions, while the reaction of the monomeric analogue N,N-dichloroacetoguanamine with alcohols does not proceed. The polymer reagent can be handled easily and recycled for further use.

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