Polarographisches Verhalten einiger (1∶1)-Komplexe des 1,5-Diphenylcarbazons
✍ Scribed by J. Zimmermann; F. Umland
- Book ID
- 112299555
- Publisher
- Springer
- Year
- 1977
- Tongue
- English
- Weight
- 170 KB
- Volume
- 286
- Category
- Article
- ISSN
- 1618-2650
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Inhaltsu È bersicht. 1,1,3,3,5,5-Hexakis(dimethylamino)-1k 5 -3k 5 -5k 5 -[1,3,5]triphosphinin (5) reagiert mit (Benzonitril) 2 PdCl 2 zu dem Chelat-Komplex Dichloro(dodeca-N-methyl-1k 5 ,3k 5 ,5k 5 -1,3,5-triphosphinin-1,1,3,3,5,5-hexaamin-C 2 ,C 4 )palladium ( ). Wird 6 in Pyridin-d 5 gelo È st, s
## Abstract The preparation of 2.5‐diphenyl‐1‐silacyclopentadienes and their reaction with iron carbonyls and π‐cyclopentadienyl‐dicarbonylcobalt yielding metal‐π‐silole complexes is described. Mass spectral data indicate the existence of an ‘aromatic’ silacyclopentadienyl species.