Polarographic reduction of sulfitobis(ethylenediamine)cobalt(III) ions
✍ Scribed by Robert D. Hargens; Woonza Min; Robert C. Henney
- Publisher
- Elsevier Science
- Year
- 1970
- Weight
- 347 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0022-0728
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✦ Synopsis
SULFITOBIS (ETHYLENEDIAMINE)COBALT(III) IONS
* To whom inquiries should be addressed. ** The cis configuration was assigned to the ion having the visible absorption maximum of shorter wavelength 4, although all the evidence is inconclusive. Baldwin, in the experimental section of his paper, calls the compound containing this ion the trans compound.
📜 SIMILAR VOLUMES
C'Saquochlorotet rammine cobatt(III) ion is irreversibly reduced at the time. Addition of amino acids shifts El/z to more positive potentials, indicating the replacement of water and chlorine at the adjacent co-ordination positions by the amino acids. The shift in El12 follows the order: Iarginine >
## Abstract Kinetics of reduction of the surfactant complex ions, __cis__‐chloro/bromo (dodecylamine)bis(ethylenediamine)cobalt(III) by iron(II) in aqueous solution was studied at 303, 308, and 313 K by spectrophotometry method under pseudo‐first‐order conditions, using an excess of the reductant.