The stability constants ofcomplexes with different stoichiometries formed by Cu(I1) with tartrate and malonate anions were determined, together with the formation constants of the mixed complexes Cu(II)-MAL-TAR. These studies were made with the help of the De Ford-Hume and Schaap-McMasters polarogra
✦ LIBER ✦
Polarographic determination of the stability constants of binary and ternary lead(II) complexes and different organic ligands
✍ Scribed by Ramon J.Barrio Diez-Caballero; Juan F.Arranz Valentin; Adela Arranz Garcia; Rafael Pardo Almudi; Pedro Sanchez Batanero
- Publisher
- Elsevier Science
- Year
- 1985
- Weight
- 466 KB
- Volume
- 196
- Category
- Article
- ISSN
- 0022-0728
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## Abstract The stopped‐flow technique was used to measure the rates of formation and dissociation of tetrahedral [ML~2~] complexes (M^2+^=Ni^2+^ or Co^2+^) of four bidentate S~2~‐donor ‘dithioimidodiphosphato’ ligands L^−^ (HL=[R^1^R^2^P(S)]NH[P(S)R^3^R^4^], R^1^ to R^4^=alkyl) at 25.0° in MeOH/