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Polarity-reversal catalysis by thiols of radical-chain hydrosilylation of alkenes

โœ Scribed by Hai-Shan Dang; Brian P. Roberts


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
198 KB
Volume
36
Category
Article
ISSN
0040-4039

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Polarity-reversal catalysis by thiols has been applied to provide an efficient method for the conversion of appropriate 1,2-diols into less or similarly stable diastereoisomers by epimerisation of their acetonides under radical-chain conditions.