Polarity of van der Waals molecules
โ Scribed by Novick, Stewart E.; Davies, Paul B.; Dyke, Thomas R.; Klemperer, William.
- Book ID
- 126793380
- Publisher
- American Chemical Society
- Year
- 1973
- Tongue
- English
- Weight
- 474 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
Ab initio calculations on twenty van der Waals dimers of small polar molecules at the experimentally observed intermolecular separation R, using Hartree-Fock molecular moments, show that the minima in the electroslatic mteraction expanded up to R-" converges to angular structures which are close to
A generalized van der Waals equation of state has been devised with a modeling of the anisotropic hard core of the molecule and assuming that the attractive van der Waals term becomes linear in density at sufficiently high densities. Corrections for non-linear density dependence have to be taken int