Polarized luminescence and structure of Van der Waals complexes of organic molecules
β Scribed by N.A. Borisevich; V.A. Povedailo; V.A. Tolkachev
- Book ID
- 107797855
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 302 KB
- Volume
- 48-49
- Category
- Article
- ISSN
- 0022-2313
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Laser-induced fluorescence excitation spectroscopy in a supersonic expansion is used to evidence intermolecular chiral discrimination at the microscopic level. Measurements have been performed in (R)-(+)-and (S)-(-)-et-methyl-2-naphthalenemethanol (a naphthalene compound made chiral by the asymmetri
Ab initio calculations on twenty van der Waals dimers of small polar molecules at the experimentally observed intermolecular separation R, using Hartree-Fock molecular moments, show that the minima in the electroslatic mteraction expanded up to R-" converges to angular structures which are close to