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Polarity effects in the solvolysis of cyclohexane derivatives. Importance of field effects in determining relative reactivities

✍ Scribed by Noyce, Donald S.; Bastian, Bruce N.; Lau, Philip T. S.; Monson, Richard S.; Weinstein, Benjamin

Book ID
126161739
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
871 KB
Volume
34
Category
Article
ISSN
0022-3263

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## Abstract When the __Hammett‐Taft__ equation log (__k/k__~o~)=ρ^q^ Β· Οƒ is applied to the solvolysis of the 3‐substituted propyl bromides **6a‐6i** in ethanol/water 4:1 __(v/v)__ log __k__ correlates linearly with Οƒ except in cases where R exerts an anchimeric effect. The reaction constant ρ^q^ fo