Rccewcd 8 SepIcmber 1981 Lumrnesccncc from complews oi the general formula Ru(N-N-N)? (N-N-N = tndcnrate N-hcrcrocychc hgmd) WJS mvcsugtcd m the range of 77-2 K lnrcrslon oi the slfn of the polmzz~~~on ratio occurred bcIo\r IS K Rcsul~s arc Interprcred III IC~IS of a rhcrmall) cqutibrclred muluple-s
โฆ LIBER โฆ
Polarisation ratios in ruthenium(II) complexes containing tridentate ligands: A comment
โ Scribed by P.S. Braterman
- Book ID
- 103022583
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 118 KB
- Volume
- 104
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The changes observed in the lifetimes and polarizations of ruthenium(U) terpyridyl complexes as low temperature are in accord with the general localised excited-state model.
Crosby and co-workers [l] have reported changes in emission polarisation on cooling below 77 K in complexes of type [Ru(ll)(N-N-N)2]
?+, where N-N-N is a tridentate N-heterocyclic ligand. Their consequent
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