The changes observed in the lifetimes and polarizations of ruthenium(U) terpyridyl complexes as low temperature are in accord with the general localised excited-state model. ## Crosby and co-workers [l] have reported changes in emission polarisation on cooling below 77 K in complexes of type [Ru(ll
Charge-transfer luminescence from ruthenium(II) complexes containing tridentate ligands
โ Scribed by M.L. Stone; G.A. Crosby
- Book ID
- 107732824
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 427 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0009-2614
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๐ SIMILAR VOLUMES
The complex Ru(i-biq)y, where i-blq IS 2.2'-bls-lsoqumolme, was synrheslzcd and srudxd spec~roscoprully rmd elrctrochemically. The strong luminescence exhibited at 77 R m rigd glasses 15 characterized as a trIplet h~ndsenrcrcd cmssion. It us the first example of hgnd-centered luminescence from a Ru(
Rccewcd 8 SepIcmber 1981 Lumrnesccncc from complews oi the general formula Ru(N-N-N)? (N-N-N = tndcnrate N-hcrcrocychc hgmd) WJS mvcsugtcd m the range of 77-2 K lnrcrslon oi the slfn of the polmzz~~~on ratio occurred bcIo\r IS K Rcsul~s arc Interprcred III IC~IS of a rhcrmall) cqutibrclred muluple-s