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Polar radicals. 17. On the mechanism of iodine atom transfer. A 9-I-2 intermediate

✍ Scribed by Tanner, Dennis D.; Reed, Darwin W.; Setiloane, B. P.


Book ID
120240219
Publisher
American Chemical Society
Year
1982
Tongue
English
Weight
873 KB
Volume
104
Category
Article
ISSN
0002-7863

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A comparison of reactivity of (EtO)2P(O)
✍ Piotr BaΕ‚czewski; Tomasz BiaΕ‚as; Aldona Szadowiak πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 76 KB

## Based on competitive reactions and 1 H NMR measurements, it was found that (EtO) 2 P(O)CH 2 I is at least 2-3 orders of magnitude less reactive than other non-phosphorus iodides of the EWG-CH 2 I type (EWG = NC, COOMe, 4-Br-C 6 H 4 CO). MeSCH 2 I turned out to be totally unreactive in the title