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Poisoning effect of SCN−, H2S and HCN on the reduction of O2 and H2O2 catalyzed by a 1:1 surface complex of Cu: 1,10-phenanthroline adsorbed on graphite electrodes, and its possible application in chemical analysis

✍ Scribed by Aldaléa L.B. Marques; Jiujun Zhang; A.B.P. Lever; William J. Pietro

Publisher: Elsevier
Year: 1995
Tongue: English
Weight: 791 KB
Volume: 392
Category: Article
ISSN: 1572-6657
DOI: 10.1016/0022-0728(95)03997-u

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Through our flow injection analysis experiments, we discovered that an unsaturated complex of \(\mathrm{Cu}\) (II) and organic ligand had a strong catalytic effect on 1.10 -phenanthroline- \(\mathrm{H}_{2} \mathrm{O}_{2}-\mathrm{CTMAB}\) chemiluminescence reaction. Based on this mechanism, the new f