PLP−SEC Study into Free-Radical Propagation Rate of Nonionized Acrylic Acid in Aqueous Solution
✍ Scribed by Lacík, Igor; Beuermann, Sabine; Buback, Michael
- Book ID
- 121320829
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 122 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0024-9297
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## Abstract Summary: Propagation rate coefficients, __k__~p~, for acrylic acid (AA) polymerization at 6 °C in aqueous solution were measured via pulsed laser polymerization (PLP) with the degree of ionization, __α__, varied over the entire range between 0 and 1. These measurements were carried out
## Abstract The propagation rate coefficients, __k__~p~, were determined for free‐radical polymerization of __N__‐vinyl formamide (NVF) in aqueous solution by pulsed‐laser‐initiated polymerization in conjunction with size‐exclusion chromatography. The polymerizations were carried out in the tempera