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Aqueous Phase Size-Exclusion-Chromatography Used for PLP−SEC Studies into Free-Radical Propagation Rate of Acrylic Acid in Aqueous Solution

✍ Scribed by Lacík, Igor; Beuermann, Sabine; Buback, Michael

Book ID: 127242071
Publisher: American Chemical Society
Year: 2001
Tongue: English
Weight: 68 KB
Volume: 34
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma002222n

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## Abstract Summary: Propagation rate coefficients, __k__~p~, for acrylic acid (AA) polymerization at 6 °C in aqueous solution were measured via pulsed laser polymerization (PLP) with the degree of ionization, __α__, varied over the entire range between 0 and 1. These measurements were carried out