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Platinum/tin catalyzed hydroformylation of naturally occurring monoterpenes

✍ Scribed by Elena V. Gusevskaya; Eduardo N. dos Santos; Rodinei Augusti; Adelson de O. Dias; Claudia M. Foca


Book ID
104424634
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
127 KB
Volume
152
Category
Article
ISSN
1381-1169

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Stereochemistry of the Platinum Catalyze
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## Abstract The deuterioformylation of (__Z__)‐ or (__E__)‐2‐butene catalyzed by [DIOP]Pt(SnCl~3~)‐ClDIOP=2,3‐__O__‐isopropylidene‐2,3‐dihydroxy‐1,4‐bis(diphenylphosphino)butane. gives predominantly __erythro__‐ or __threo__‐1,3‐[^2^H]~2~‐2‐methylbutanal respectively. Hence, hydroformylation by th