Palladium/tin catalyzed alkoxycarbonylation of naturally occurring bicyclic monoterpenes
✍ Scribed by Lı́lian L. da Rocha; Adelson de O. Dias; Eduardo N. dos Santos; Rodinei Augusti; Elena Gusevskaya
- Book ID
- 104423621
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 137 KB
- Volume
- 132
- Category
- Article
- ISSN
- 1381-1169
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The palladium-catalyzed alkoxycarbonylation of allyl carbonates and allyl chlorides derivatives from terpenic olefins was carried out under atmospheric pressure of carbon monoxide and at moderate temperature. The reaction offers a very good method for the preparation of new , ␥-unsaturated esters a
Limonene can be efficiently and selectively oxidized by dioxygen at 6040°C in glacial acetic acid containing LiCl, in the presence of the PdCl,-CuCl, catalytic combination, giving rise to the fonaatioa ofrmu.T~acetareasthe~ product. Several concurrent transformations of limoncne occur in the reactio