Platinum(II) Complexes with Porphyrin Ligands—Additive Cytotoxic and Photodynamic Effect
✍ Scribed by Prof. Dr. Henri Brunner; Dr. Herbert Obermeier
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 247 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
✦ Synopsis
COMMUNICATIONS
(m)-1612 (m), 1571 (w). 1456 (m). 1295 ( w ) , 1242 (m), 881 (m). 852 (s)cm-': UV:VIS (CH,OH): ;.mdx(t:) = 206 (41 000). 278 nm (1700).
📜 SIMILAR VOLUMES
Eight molecules with different conformations are present in the unit cell of the Pt complex 1, which contains a mismatched arrangement of the chiral ligands Chiraphos and Binol (i.e., (S,S)-Chiraphos prefers the δ conformation, whereas (R)-Binol tends to induce the λ conformation in the diphosphane)
## Abstract Several palladium(II) and platinum(II) complexes analogous to oxaliplatin, bearing the enantiomerically pure (1__R__,2__R__)‐(−)‐1,2‐diaminocyclohexane (DACH) ligand, of the general formula {MX~2~[(1__R__,2__R__)‐DACH]}, where M = Pd or Pt, X $= {1 \over 2}$ (COO)~2~, ${1 \over 2}$ CH~2