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Platinum(II) Complexes of Cyclic Triphosphenium Ions: a 31 P NMR Spectroscopic and Computational Study

✍ Scribed by Coffer (née Monks), Philippa K.; Deng, Robert M. K.; Dillon, Keith B.; Fox, Mark A.; Olivey, Richard J.


Book ID
120277815
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
874 KB
Volume
51
Category
Article
ISSN
0020-1669

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Reaction of a cyclic triphosphenium ion
✍ Alice J. Boyall; Keith B. Dillon; Philippa K. Monks; Jennifer C. Potts 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 178 KB

## Abstract The di‐ium dication formed by triflic acid protonation of the cyclic triphosphenium ion derived from 1,4‐bis‐diphenylphosphinobutane, (dppb), and P~3~(X = Br or Cl) decomposes via an acyclic dication bearing a PHX group; this intermediate is reduced by SnX~2~ in the presence of HX to y