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Platinum(II) and Palladium(II) Bis(chelate) Complexes Containing both Tri(1-cyclohepta-2, 4, 6-trienyl)phosphane, P(C7H7)3, and Dichalcogenolato Ligands

โœ Scribed by Max Herberhold; Thomas Schmalz; Wolfgang Milius; Bernd Wrackmeyer


Publisher
John Wiley and Sons
Year
2002
Tongue
German
Weight
165 KB
Volume
628
Category
Article
ISSN
0372-7874

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The olefinic phosphane P(C 7 H 7 ) 3 (5) behaves as a tetradentate tripod ligand in [RhCl{P(g 2 -C 7 H 7 ) 3 }] (6), using all 3 cyclohepta-2,4,6-trienyl substituents as g 2 -coordinating side-arms. Nucleophilic displacement of the one-electron chloro ligand by halides or pseudohalides to give [RhX{

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New Dimetallic Palladium and Platinum Co
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