Platinum-silver clusters: synthesis and crystal structure of [Pt3Ag(μ-CO)3(PPh3)5]ClO4 · 2H2O
✍ Scribed by Sumit Bhaduri; Krishna Sharma; Peter G. Jones; Cristina Freire Erdbrügger
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 223 KB
- Volume
- 326
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
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IPt,(dpPy),(Cc3-S),Ag3(Cc3-S)2Ptz(dPPY)41
The reactions of [Pt3R~6(CO),l(p-H)3(p3-H)] (1) with PMe3 and PPh3 have produced the salts [Pt(PR3)3H]-[Pt3R~6(CO)2,(p3-H)(p-H)2]r 5a and 5d, R = Me and Ph in the yields 9% and 22%, respectively. By contrast the reaction of 1 with PPh, in the presence of Me3N0 has yielded the phosphane-substituted d
## Dedicated to Prof. Huns-Georg uon Schnering on the occasion of his 60th birthday (1 7.V. 9 I) The cluster compounds [Pt,(,u-CO),(PR,),] act as Lewis bases towards the metal halides of Group XI, MX, Group XII, MX,, and Group XIII, MX,, to form cluster compounds of the composition [{MX,}{Pt3(,u-