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Platinum-Catalyzed Substitution of Allylic Fluorides

✍ Scribed by Benedetto, Elena; Keita, Massaba; Tredwell, Matthew; Hollingworth, Charlotte; Brown, John M.; Gouverneur, Véronique


Book ID
126258658
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
738 KB
Volume
31
Category
Article
ISSN
0276-7333

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The new Mo(II) triflate complex 5 has been found to catalyze the C-C bond forming allylic substitution with silyl enol ethers derived from [i-dicarbonyls (e.g., 6 + 12 ---> 14) and from simple ketones (e.g., 6 + 13 ---> 16) as nucleophiles.

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