First-Row Transition Metal Bis(amidinate
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Christian A. Nijhuis; Erica Jellema; Timo J. J. Sciarone; Auke Meetsma; Peter H.
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Article
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2005
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John Wiley and Sons
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English
β 198 KB
## Abstract The sterically hindered benzamidinate ligand [PhC(NAr)~2~]^β^ (Ar = 2,6β__i__Pr~2~C~6~H~3~) has been employed to prepare bis(amidinate) complexes [{PhC(NAr)~2~}~2~M] of the divalent firstβrow transition metals CrβNi (1β5). For Cr (planar), Mn and Co (tetrahedral) the observed structures