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Reactions of Coordinated Ligands. VI. Metal Ion Control in the Synthesis of Planar Nickel(II) Complexes of α-Diketo-bis-mercaptoimines

✍ Scribed by Thompson, Major C.; Busch, Daryle H.


Book ID
127249021
Publisher
American Chemical Society
Year
1964
Tongue
English
Weight
741 KB
Volume
86
Category
Article
ISSN
0002-7863

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Nickel(II) Complexes of Chiral Tripodal
✍ Berkessel, Albrecht ;Seidel, Lutz ;Bats, Jan W. ;Bolte, Michael ;Neumann, Thomas 📂 Article 📅 1997 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 683 KB

The complexation behavior of three chiral, tripodal N,O,Sligands with nickel(I1) salts was examined. It was found that the coordination mode of the ligands (bidentate N,O and N,S; tridentate N,O,S) and of the central nickel ion (square-planar vs. pseudo-octahedral) is not simply an intrinsic propert