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Planar Fe6 Cluster Units in the Crystal Structure of RE15Fe8C25 (RE=Y, Dy, Ho, Er)

✍ Scribed by Bambar Davaasuren; Horst Borrmann; Enkhtsetseg Dashjav; Guido Kreiner; Michael Widom; Walter Schnelle; Frank R. Wagner; Rüdiger Kniep

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 867 KB
Volume: 49
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.201002338

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Eleven new rare-earth antimonides and bismuthides RE 5 M 2 X (see Table 1) have been synthesized and characterized by X-ray powder methods. The compounds are isostructural to the previously reported pnictides RE 5 M 2 X and adopt the Mo 5 B 2 Si structure (space group I4/mcm, an ordered version of C