The first ‘alkane-like’ functionalizatio
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Alexander V. Orlinkov; Nikolai D. Kagramanov; Pavel V. Petrovskii; Irena S. Akhr
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Article
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2010
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Elsevier Science
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French
⚖ 253 KB
Selective one-pot functionalization of linear alkyl acetates C n H 2n + 1 OCOMe (n = 6, 8), with CO and various nucleophilic substrates (iso-propanol, morpholine, piperidine, and anisole) in the presence of the superelectrophilic system CBr 4 Á2AlBr 3 is performed for the first time.