✦ LIBER ✦
The first ‘alkane-like’ functionalization of n-alkyl acetates: a new method for one-pot selective syntheses of bifunctional aliphatic compounds with an acetate group
✍ Scribed by Alexander V. Orlinkov; Nikolai D. Kagramanov; Pavel V. Petrovskii; Irena S. Akhrem
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- French
- Weight
- 253 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Selective one-pot functionalization of linear alkyl acetates C n H 2n + 1 OCOMe (n = 6, 8), with CO and various nucleophilic substrates (iso-propanol, morpholine, piperidine, and anisole) in the presence of the superelectrophilic system CBr 4 Á2AlBr 3 is performed for the first time.