๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Picosecond time-resolved absorption study of all-trans- and 9-cis-retinal: configurational relaxation in the triplet state

โœ Scribed by Yoshinori Hirata; Noboru Mataga; Yumiko Mukai; Yasushi Koyama

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
390 KB
Volume
134
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

โœฆ Synopsis

Picosecond time-resolved absorption spectra of all-tram-and 9-cis-retinal in n-hexane solution have been measured by using an Nd3+:YAG laser photolysis system. A drastic change of the T,+T, absorption spectrum of the 9-cis isomer has been observed in the picosecond to nanosecond time region, which should reflect the configurational relaxation in the triplet state.

๐Ÿ“œ SIMILAR VOLUMES

Picosecond time-resolved fluorescence st
Picosecond time-resolved fluorescence study of all-trans retinal. The existence of two fluorescent singlet excited states
โœ Tahei Tahara; Hiro-o Hamaguchi ๐Ÿ“‚ Article ๐Ÿ“… 1995 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 395 KB

Picosecond time-resolved fluorescence spectra of all-trans retinal in hexane have been measured with 8 ps time-resolution with use of a highly sensitive streak camera. The observed fluorescence consists of a fast (r < 1 ps, ,h.ma x m 470 nm) and a slow (r = 33-34 ps, Ama x --540 nm) component. The l

Time-resolved absorption spectroscopy of
Time-resolved absorption spectroscopy of the triplet state produced from the all-trans, 7-cis, 9-cis, 13-cis, and 15-cis isomers of ฮฒ-carotene
โœ Hideki Hashimoto; Yasushi Koyama; Kouichi Ichimura; Takayoshi Kobayashi ๐Ÿ“‚ Article ๐Ÿ“… 1989 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 497 KB

Time-resolved absorption spectroscopy was applied to the triplet species produced by anthracene-sensitized flash photolysis of the all-trans, 7-c&, 9-c& 13-c& and 1 S-cis isomers of g-carotene. Upon triplet excitation, the a&trans and 154s isomers produced an identical triplet species showing the sa

Torsional relaxations from perpendicular
Torsional relaxations from perpendicular to tilted configurations in the intramolecular charge transfer of excited 9,9โ€ฒ-bianthryl as studied by femtosecond-picosecond time-resolved absorption spectral measurements in solution
โœ Noboru Mataga; Shinya Nishikawa; Tadashi Okada ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 547 KB

Femtosecond-picosecond time-resolved absorption spectral measurements on 9,9'-bianthryl in polar alkanenitrile solvents revealed that the rise curve of the charge-transfer (CT) state contained components with rise times considerably longer than the solvent 7L, which indicated the importance of the t