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Picosecond radical kinetics. Rate constants for reaction of benzeneselenol with primary alkyl radicals and calibration of the 6-cyano-5-hexenyl radical cyclization

โœ Scribed by Newcomb, Martin; Varick, Thomas R.; Ha, Chau; Manek, M. Beata; Yue, Xu


Book ID
126180820
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
780 KB
Volume
114
Category
Article
ISSN
0002-7863

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โœ John F. Garst; Franklin E. Barton II ๐Ÿ“‚ Article ๐Ÿ“… 1969 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 245 KB

Reactions of sodium naphthalenide with alkyl chlorides, bromides, and iodides produce free alkyl radicals which subsequently react with sodium naphthalenide, generating alkylsodiums through electron-transfer and alkylated naphthalenides through radical combination (l-7). 5-Hexenyl halides have playe