We report the duect measurement of electron solvatlon tunes m methanol and ethanol. A plcosecond techmque utihzmg a laser-trqgered flash lamp and a streak camera IS used to momtor the solvation process. The relationship of the solvatlon dynamics to dlelectrx relaxation. local hestmg. and pulse-radio
Picosecond proton transfer studies in water-alcohols solutions
β Scribed by D. Huppert; E. Kolodney
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 846 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0301-0104
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
We consider models for proton transfer reactions in solution. We present the derivation of the different models and illustrate the problems involved with the different approaches. When determining the rate constants, we utilize the solvent response method using either Hartree-Fock or multiconfigurat
The time evolution of the sokated electron in a series of linear aicohok has been measured. A correlation between the time for monomer rotation TV and the solvation time r, seems to hold for the series. The mechanism of salvation is discussed with reference to the experimental data. J Following the
Picosecond as well as femtosecond transient absorption measurements have been performed on eight water-soluble heterodimers consisting of combinations of oppositely charged free base and metal porphyrins which have been electrochemically characterized. The ultrafast non-exponential absorption increa