Picosecond dynamics of double proton transfer in 7-azaindole dimers
β Scribed by W.M. Hetherington III; R.H. Micheels; K.E. Eisenthal
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 352 KB
- Volume
- 66
- Category
- Article
- ISSN
- 0009-2614
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π SIMILAR VOLUMES
Fluorescence lifetime measurements of purified 7-azaindole in methanol and butanol as a function of temperature are performed. The results indicate that in alcohols there exists a population of 'I-azaindole that is solvated in such a way that excitedstate tautomerixation is no longer a viable mode o
I-or the 7azaindole dimer (ND) in 3-methylpentane. the metastable ground-state dimeric tautomer generated through an exIted\_state double proton transfer and its subsequent reIaxation was detected by transient absorption and twostep laser excitation fluorescence spectroscopies. The second laser exci
## Abstract __Protonβtransfer reactions of the radical anion and cation of the 7βAzaindole (7AI) dimer were investigated by means of density functional theory (DFT). The calculated results for the dimer anion and cation were very similar. Three equilibrium structures, which correspond to the nonβpr