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Picosecond flash photolysis of carbonyl complexes of ruthenium(II) porphyrin .pi. cation radicals

โœ Scribed by Barley, Mark; Dolphin, David; James, Brian R.; Kirmaier, Christine; Holten, Dewey

Book ID
126003789
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
934 KB
Volume
106
Category
Article
ISSN
0002-7863

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Picosecond flash-photolysis of Ni(II)- a
Picosecond flash-photolysis of Ni(II)- and Ag(II)-porphyrins
โœ V.S. Chirvonyi; B.M. Dzhagarov; Yu.V. Timinskii; G.P. Gurinovich ๐Ÿ“‚ Article ๐Ÿ“… 1980 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 485 KB

Photoevcltatlon of NI(II)-and A&II)-porphyrms with a 10 ps pulse at 530 nm produces a new transient absorptIonThe transient species hfetunes were 250 f. 50 ps and 15 +-8 ps for Nr and Ag-porphyrins, respectwely. It is shown that the triplet state 15 responsible for Uus absorption in Ag-porphyrin. 1.